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101.
Volkan Kumtepeli Yulong Zhao Maik Naumann Anshuman Tripathi Youyi Wang Andreas Jossen Holger Hesse 《国际能源研究杂志》2019,43(9):4127-4147
The rapid increase of renewable energy sources made coordinated control of the distributed and intermittent generation units a more demanded task. Matching demand and supply is particularly challenging in islanded microgrids. In this study, we have demonstrated a mixed‐integer quadratic programming (MIQP) method to achieve efficient use of sources within an islanded microgrid. A unique objective function involving fuel consumption of diesel generator, degradation in a lithium‐ion battery energy storage system, carbon emissions, load shifting, and curtailment of the renewable sources is constructed, and an optimal operating point is pursued using the MIQP approach. A systematic and extensive methodology for building the objective function is given in a sequential and explicit manner with an emphasis on a novel model‐based battery aging formulation. Performance of the designed system and a sensitivity analysis of resulting battery dispatch, diesel generator usage, and storage aging against a range of optimization parameters are presented by considering real‐world specifications of the Semakau Island, an island in the vicinity of Singapore. 相似文献
102.
Shipra Jain Jyoti Shah Nainjeet Singh Negi Chhemendra Sharma Ravinder Kumar Kotnala 《国际能源研究杂志》2019,43(9):4743-4755
Recent increase in energy demand and associated environmental degradation concern has triggered more research towards alternative green energy sources. Eco‐friendly energy in facile way has been generated from abundantly available iron oxides using only few microliters of water without any external energy source. Hydroelectric cell (HEC) compatible to environment benign, low cost oxygen‐deficient mesoporous hematite nanoparticles has been used for splitting water molecules spontaneously to generate green electricity. Hematite nanoparticles have been synthesized by coprecipitation method. Chemidissociated hydroxyl group presence on hematite surface has been confirmed by infrared spectroscopy (IR) and X‐ray photoelectron spectroscopy (XPS). Surface oxygen vacancies in nanostructured hematite have been identified by transmission electron microscopy (TEM), XPS, and photoluminescence (PL) measurement. Hematite‐based HEC delivers 30 mA current with 0.92 V emf using approximately 500 μL water. Maximum off‐load output power 27.6 mW delivered by 4.84 cm2 area hematite‐based HEC is 3.52 times higher than reported 7.84 mW power generated by Li‐magnesium ferrite HEC. Electrochemistry of HEC in different irreversible polarization loss regions has been estimated by applying empirical modeling on V‐I polarization curve revealing the reaction and charge transport mechanism of cell. Tafel slope 22.7 mV has been calculated by modeling of activation polarization overvoltage region of 0.11 V. Low activation polarization indicated easy charge/ion diffusion and faster reaction kinetics of Ag/Zn electrode owing to lesser energy barrier at interface. Dissociated H3O+ ions diffuse through surface via proton hopping, while OH? ions migrate through interconnected defective crystallite boundaries resulting into high output cell current. 相似文献
103.
Potassium ion batteries (PIBs) are promising alternatives to Li‐ion batteries due to the abundance of potassium. However, the development of PIBs is in its early stages, and only a few anode materials have been reported. Herein, we explored anode materials for PIBs using high‐throughput computational screening. The alloying and conversion reactions of prospective anode materials were investigated using the Materials Project database. Grand potential diagrams were obtained to examine the reaction potential and theoretical capacity of the anode materials. Calculation results indicated that P, As, Si, and Sb anodes exhibited high theoretical capacities. In addition, the screening results revealed that phosphides generally exhibit a lower reaction potential compared with those of sulfides and oxides. A total of 18 binary compounds that exhibited a high theoretical capacity and a low reaction potential (greater than 450 mAh/g and 0.7 V) were identified as promising anode materials for PIBs. In particular, ZnP2, CuP2, SiP, NiP3, CoP3, V3S4, Nb3S5, Bi2O3, and Ga2O3 exhibited high theoretical capacities. 相似文献
104.
MAO Jianzhao GAO Huihui XUE Runping YANG Chen LIU Pengqing XU Jianjun CHEN Sheng JIANG Mengjin 《储能科学与技术》2019,8(2):304-310
以硫酸肼(HS)、对苯二甲酸(TPA)、4,4'-联苯醚二甲酸(DPE)为单体,发烟硫酸做溶剂和脱水剂一步合成了一系列不同TPA和DPE单体配比的磺化聚芳噁二唑(SPOD),再通过氢氧化锂中和得到聚芳噁二唑磺酸锂(Li-SPOD)聚合物电解质,采用浇铸成膜法制得Li-SPOD电解质膜,研究改变TPA和DPE两种单体配比对Li-SPOD结构及性能的影响。结果表明,几种不同单体配比均能实现在聚合过程中一步得到SPOD,磺酸基团接枝在DPE结构的苯环上,并且可以达到理论接枝量;同时Li-SPOD电解质膜的聚集态结构差异很小;热性能的表现均非常优异,初始热分解温度都在450 ℃以上;力学性能随DPE单体含量的增加稍有下降但依然保持在较高的水平;电导率约为10-5S/cm级别,随DPE含量增加而逐渐降低;Li-SPOD固态电解质电化学稳定性较好,对锂稳定电化学窗口均在4.0 V以上。 相似文献
105.
Yuhui Ma Yuanhang Cheng Xiuwen Xu Menglin Li Chujun Zhang Sin Hang Cheung Zixin Zeng Dong Shen Yue-Min Xie Ka Lok Chiu Fen Lin Shu Kong So Chun-Sing Lee Sai-Wing Tsang 《Advanced functional materials》2021,31(3):2006802
Passivation of organometal halide perovskites with polar molecules has been recently demonstrated to improve the photovoltaic device efficiency and stability. However, the mechanism is still elusive. Here, it is found that both polymers with large and small dipole moment of 3.7 D and 0.6 D have negligible defect passivation effect on the MAPbI3 perovskite films as evidenced by photothermal deflection spectroscopy. The photovoltaic devices with and without the polymer additives also have comparable power conversion efficiencies around 19%. However, devices with the additives have noticeable improvement in stability under continuous light irradiation. It is found that although the initial mobile ion concentrations are comparable in both devices with and without the additives, the additives can strongly suppress the ion migration during the device operation. This contributes to the significantly enhanced electrical-field stress tolerance of the perovskite solar cells (PVSCs). The PVSCs with polymer additives can operate up to −2 V reverse voltage bias which is much larger than the breakdown voltage of −0.5 V that has been commonly observed. This study provides insight into the role of additives in perovskites and the corresponding device degradation mechanism. 相似文献
106.
《International Journal of Hydrogen Energy》2021,46(60):30818-30827
In this paper, dopamine hydrochloride (DPH) is introduced to synthesize ZIF-8@ZIF-67@DPH in the preparation of ZIF-8@ZIF-67. ZnSe/CoSe/NCDPH (N-doped carbon) composites are calcined in a high-temperature inert atmosphere with ZIF-8@ZIF-67@DPH as the precursor, selenium powder as the selenium source. ZnSe/CoSe/NCDPH has high discharge specific capacity, good cycle stability and outstanding rate performance. The first discharge capacity of ZnSe/CoSe/NCDPH is 1616.6 mAh g−1 at the current density of 0.1 A g−1, and the reversible capacity remains at 1214.2 mAh g−1 after 100 cycles, the reversible capacity is 416.7 mAh g−1 after 1000 cycles at 1 A g−1. Therefore, ZnSe/CoSe/NCDPH composites provide a new step for the research and synthesis of new stable, high-capacity, and safe high-performance lithium ion batteries. The bimetallic selenide composites not only have bimetallic active sites, but also can form synergistic effect between different metal phases, which can effectively reduce the capacity attenuation caused by volume expansion and reactive stress enrichment during lithium storage of metal oxide anode materials. Meanwhile, N-doped carbon can improve the conductivity and provide more active sites to store lithium, thus improving its lithium storage capacity. 相似文献
107.
Changbai Long Huiqing Fan Wei Ren Jinyan Zhao 《Journal of the European Ceramic Society》2019,39(14):4103-4112
This work reports the existence of double polarization hysteresis (P–E) loop in Aurivillius-phase ferroelectric Bi4Ti3O12 (BiT) and reveals dramatic influence of small compositional variations on the electrical properties of it. The double polarization hysteresis is a characteristic of the interaction of defects with domain walls. This characteristic becomes more pronounced in Bi-deficient and Mg-doped BiT due to an increase in oxygen vacancy concentration at the lattices. Normal and saturated P–E loop is recalled by Nb donor doping, and associated composition Bi4Ti2.97Nb0.03O12.015 (BiT-0.03Nb) shows high remnant polarization (Pr = 12.5 μC/cm2) and large field-induced strain (S33 = 5.6 × 10?4). In addition, this doping results in bulk conductivity (σb) of BiT decreasing dramatically and associated activity energy (Ea) increasing significantly. In contrast, high oxide ion conductivity is induced with Mg2+ acceptor doping, and at 600 °C the optimum composition has ionic conductivity of ?0.65 × 10?2 S cm?1 in the bulk. 相似文献
108.
Junzhe Li Shao-hua Luo Yang Sun Jiayu Li Jun Zhang Ting-Feng Yi 《Ceramics International》2019,45(4):4849-4856
Sodium-substituted LiMnPO4/C/reduced graphene oxide (LNMP@rGO) was synthesized in this study via freeze drying and carbon thermal reduction method with graphene oxide as carbon source. Sodium ion doping is optimized and rGO effects are evaluated by XRD, SEM, TEM, BET, Raman, and electrochemical performance measurements. Well-distributed nanoparticles with average size of ~50?nm are evenly distributed on the surface or intercalation between rGO layers, resulting in a porous ion/electronic conductive network. Compared to 122.3?mA?h?g?1 in unmodified LNMP, the best LNMP@rGO (20?mg rGO) exhibits an excellent initial discharge capacity of 150.4?mA?h?g?1 at 0.05?C at 122.9% of the initial capacity. The capacity retention rate is 95.8% of the initial capacity after 100 cycles at 1?C. Capacity of 101.2?mA?h?g?1 is preserved even at rates as high as 10?C. 相似文献
109.
Kosuke Sato Akihiko Kono Hiroaki Urushibata Yoji Fujita Masato Koyama 《Electrical Engineering in Japan》2019,208(3-4):48-63
The authors developed a physics‐based equivalent circuit model of a lithium‐ion battery (LIB) whose parameters are continually updated, reflecting the theoretical calculation results of the Butler‐Volmer equation, diffusion equations of the lithium‐ion and lithium, and Nernst equations of the liquid and solid phases. The developed model was applied to the charge/discharge simulations of an LIB, and the experimental and simulated results of constant current discharges and pulsed‐charge/discharge were found to be in excellent agreement. In particular, using the developed model, analyzing transient responses of the LIB derived from the transition of the electric double layer charging to the electrode reaction is possible. These results demonstrate that the electrochemical performance of an LIB can be calculated on a circuit simulator using the developed model. 相似文献
110.
Yu Cao Jiayu Li Jun Liu Hongbo Liu Yan Jiang Hongwen Zhang 《Polymer International》2019,68(4):694-699
A novel ion‐imprinted polymer (IIP) using (6‐O‐butene diacid ester)‐β‐cyclodextrin (β‐CD‐MAH) as the functional monomer and copper ions as the template was developed for Cu2+ sensing. First, reactive β‐cyclodextrin (β‐CD) monomers with vinyl carboxylic acid functional groups were synthesised and were co‐polymerised with styrene via radical polymerisation. Then, the β‐CD copolymers were complexed with Cu2+ in order to obtain the IIP. The imprinting effect was realised by removing the template ions from the imprinted polymer. The structure, composition and morphology of the IIP were characterised by Fourier transform IR spectroscopy, energy‐dispersive spectroscopy and field‐emission SEM. The adsorption capacity was investigated by UV–visible spectroscopy in batch operation mode. The maximum adsorption capacity for the Cu2+ template ions was 28.91 mg g?1, and the adsorption selectivity was clearly illustrated from the increased sorption affinity towards Cu2+ ions over other competing ions. The adsorption was affected by the pH of the aqueous medium, and enhanced adsorption capacity was observed at pH 5. The prepared IIP could be used 10 times after its regeneration without significant loss of the adsorption capacity. © 2018 Society of Chemical Industry 相似文献